Solid substances that produce a flammable gas when wet or react violently with water. Known examples include sodium, calcium, potassium, lithium and calcium carbide. Please note, attempting to put out a fire involving dangerous when wet materials with water will only make the situation worse. Special “Class D” fire extinguishers are required for use with dangerous when wet substance
Handling and Storage Guidelines
Similarly, to flammable, pyrophoric, and self-heating materials, the same handling guidelines applies to dangerous when wet materials. It is important to note that any paper toweling, Kim wipes, gloves, etc., that have come into contact with these materials need to be quenched with water before disposal. When working with these materials, make sure that all glassware and equipment is completely dry before use. An SOP and Risk Assessment should be prepared for each process involving pyrophoric or water-reactive materials and always perform a dry-run without any chemicals of the experiment.
For storage, always check Section 7 of the SDS for storage guidelines. Keep the container dry and store in appropriate cabinets. Never store near any water sources.
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- Introduction and Purpose
- Employee Information and Training
- Safe Chemical Use
- Globally Harmonized System (GHS)
- National Fire Protection Agency (NFPA) Diamond
- Safety Data Sheets
- Minimize Exposure to Chemicals
- Routes of Chemical Entry
- Chemical Exposure Limits
- Chemical Exposure Monitoring
- Toxicity
- Chemical Labeling
- General Storage Guidelines
- Transportation of Chemicals
- Chemical Segregation
- Chemical Hazards
- Particularly Hazardous Substances
- Control Measures
- Physical Hazards
- Emergencies and Exposures
- Other Hazards
- Hazardous Chemical Waste Disposal
- Record Keeping
- Appendix A: Globe Selection
- Appendix B: Chemical Segregation
- Appendix C: Particularly Hazardous Substances
- Appendix D: Information on Chemical Exposures from Health Hazards
- Appendix E: Standard Operating Procedures Guide
- Appendix F: Safe Use of Pyrophoric Reagents
- Appendix G: Information on Controlled Substances
- Appendix H: Risk Assessment Guide
- Appendix I: Laboratory Emergency Readiness Guide
- Appendix J: Inspection Guide
- Appendix K: Chemical Inventory Guide
- Appendix L: Lab Equipment Guide
- Appendix M: Laboratory Management Guide
- Appendix N: Reproductive Health
- Chemical Hygiene Resources and References
- Glossary